Please use this identifier to cite or link to this item: https://ir.swu.ac.th/jspui/handle/123456789/13254
ชื่อเรื่อง: Characterization of the optimal catalytic pyrolysis conditions for bio-oil production from brown salwood (Acacia mangium Willd) residues
ผู้แต่ง: Charusiri W.
Numcharoenpinij N.
Keywords: Catalysts
Flow of gases
Nitrogen
Optimization
Product design
Pyrolysis
Regression analysis
Residence time distribution
Statistics
Surface properties
Temperature
Bio oil
Box-Behnken
Brown salwood
Catalytic pyrolysis
Response surface methodology
Petroleum industry
analytical method
biomass
catalysis
catalyst
dicotyledon
dolomite
experimental design
flow velocity
nitrogen
oil production
optimization
plant residue
pyrolysis
residence time
response surface methodology
temperature effect
Acacia mangium
วันที่เผยแพร่: 2017
บทคัดย่อ: Fast growing trees have recently attracted interest as a possible feedstock for bio-energy because they are environmentally friendly and provide a sustainable energy source. This work demonstrated the production of bio-oil and related chemicals by the catalytic pyrolysis of brown salwood (Acacia mangium Willd) residue in a continuous pyrolysis reactor using 1.00 wt % of dolomite catalyst. The effects of temperature (440–580 °C), biomass feed rate (0.3–0.9 kg h−1), and nitrogen gas flow rate (80–160 cm3 min−1) and their reciprocal interaction were determined; these parameters were adjusted systematically to optimize the experimental design using Box-Behnken design. Response surface methodology based on 3 levels of experimental design was used to determine the parameters that affected the production of bio-oil and the product distribution. The optimum conditions were determined to be a reaction temperature of 540 °C, a biomass feed rate of 0.45 kg h−1 and a nitrogen gas flow rate of 155.00 cm3 min−1 with a constant amount of 1.0 wt% dolomite catalyst. We obtained a maximum bio-oil yield of 44.78 ± 0.47 wt% through the use of response surface methodology. The modified quadratic regression model revealed the optimal application of temperature and feed rate in accordance with the residence time; meanwhile, the nitrogen gas flow rate was also considered. The bio-oil was characterized using GC-MS, FTIR, and physicochemical and elemental analyses. Brown salwood residues were shown to be applicable to thermal processes, and catalytic pyrolysis was shown to be a potential candidate to produce bio-oil and value-added chemicals for several applications. © 2017 Elsevier Ltd
URI: https://ir.swu.ac.th/jspui/handle/123456789/13254
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85028530676&doi=10.1016%2fj.biombioe.2017.08.030&partnerID=40&md5=503a1a58d0a890ca93db0de7cd3f62bb
ISSN: 9619534
Appears in Collections:Scopus 1983-2021

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