Publication: Flammability and thermomechanical properties of dianhydride-modified polybenzoxazine composites reinforced with carbon fiber
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Issued Date
2013
Resource Type
File Type
application/pdf
ISSN
2728397
DOI
Other identifier(s)
2-s2.0-84888012673
Rights Holder(s)
Scopus
Bibliographic Citation
Polymer Composites. Vol 34, No.12 (2013), p.2067-2075
Suggested Citation
Jubsilp C., Panyawanitchakun C., Rimdusit S. Flammability and thermomechanical properties of dianhydride-modified polybenzoxazine composites reinforced with carbon fiber. Polymer Composites. Vol 34, No.12 (2013), p.2067-2075. doi:10.1002/pc.22615 Retrieved from: https://hdl.handle.net/20.500.14740/6505
Author(s)
Abstract
Composites based on carbon fiber (CF) and benzoxazine (BA-a) modified with PMDA were investigated. The flammability of the carbon fiber composites was examined by limiting oxygen index (LOI) and UL-94 vertical tests. The LOI values increased from 26.0 for the CF/poly(BA-a) composite to 49.5 for the CF-reinforced BA-a/PMDA composites as thin as 1.0 mm and the CF-reinforced BA-a/PMDA composites were also achieved the maximum V-0 fire resistant classification. Moreover, the incorporation of the PMDA into poly(BA-a) matrix significantly enhanced the Tg and the storage modulus (E') values of the CF-reinforced BA-a/PMDA composites rather than those of the CF/poly(BA-a). The Tg values and storage moduli of the obtained CF-reinforced BA-a/PMDA composites were found to have relatively high value up to 237°C and 46 GPa, respectively. The CF-reinforced BA-a/PMDA composites exhibited relatively high degradation temperature up to 498°C and substantial enhancement in char yield with a value of up to 82%, which are somewhat higher compared to those of the CF/poly(BA-a) composite, i.e., 405°C and 75.7%, respectively. Therefore, due to the improvement in flame retardant, mechanical and thermal properties, the obtained CF-reinforced BA-a/PMDA composites exhibited high potential applications in advanced composite materials that required mechanical integrity and self-extinguishing property. © 2013 Society of Plastics Engineers.