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Scandium(III)-Triflate-Catalyzed Pinacol-Pinacolone Rearrangement and Cyclization of 1,2-Diaryl-1,2-Ethanediol: A Versatile Synthesis of 1-Aryl-2,3-Dihydro-1H-3-Benzazepines

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dc.contributor.authorIeawsuwan W.
dc.contributor.authorPingaew R.
dc.contributor.authorKunkaewom S.
dc.contributor.authorPloypradith P.
dc.contributor.authorRuchirawat S.
dc.date.accessioned2021-04-05T03:02:49Z
dc.date.available2021-04-05T03:02:49Z
dc.date.issued2019
dc.date.issuedBE2562
dc.description.abstractAn efficient scandium(III)-triflate-catalyzed pinacol-pinacolone rearrangement and cyclization of 1,2-diaryl-1,2-ethanediol has been developed, providing a variety of 2,3-dihydro-1H-3-benzazepine derivatives in good yields. The obtained products could be transformed to other valuable building blocks for the synthesis of some biologically active compounds or natural products. Moreover, this protocol was also successfully employed for the synthesis of the corresponding 1-phenyl-3,4,5,6-tetrahydrobenzo[d]azocine and 3-phenylisoquinoline products. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
dc.format.mimetypeapplication/pdf
dc.identifier.citationAsian Journal of Organic Chemistry. Vol 8, No.8 (2019), p.1441-1447
dc.identifier.doi10.1002/ajoc.201900318
dc.identifier.issn21935807
dc.identifier.other2-s2.0-85069704529
dc.identifier.urihttps://hdl.handle.net/20.500.14740/5202
dc.rights.holderScopus
dc.titleScandium(III)-Triflate-Catalyzed Pinacol-Pinacolone Rearrangement and Cyclization of 1,2-Diaryl-1,2-Ethanediol: A Versatile Synthesis of 1-Aryl-2,3-Dihydro-1H-3-Benzazepines
dc.typeArticle
dspace.entity.typePublication
swu.datasource.scopushttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85069704529&doi=10.1002%2fajoc.201900318&partnerID=40&md5=de1197bbad57176134c8ce6ffa94545c

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