Publication:
Tetrakis(μ-4-chlorophenoxyacetato-κ2O,O′) -dimolybdenum(II)

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Issued Date

2006

Resource Type

Article

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application/pdf

ISSN

16005368

DOI

10.1107/S1600536805015795

Other identifier(s)

2-s2.0-32244446559

Rights Holder(s)

Scopus

Bibliographic Citation

Acta Crystallographica Section E: Structure Reports Online. Vol 61, No.6 (2006), p.m1191-m1193

Suggested Citation

Liwporncharoenvong T., Luck R.L. Tetrakis(μ-4-chlorophenoxyacetato-κ2O,O′) -dimolybdenum(II). Acta Crystallographica Section E: Structure Reports Online. Vol 61, No.6 (2006), p.m1191-m1193. doi:10.1107/S1600536805015795 Retrieved from: https://hdl.handle.net/20.500.14740/5655

Title

Tetrakis(μ-4-chlorophenoxyacetato-κ2O,O′) -dimolybdenum(II)

Author(s)

Liwporncharoenvong T.
 Luck R.L.

Abstract

The crystal structure determination of the title compound, [Mo 2(C8H6ClO3)4], confirms the existence of a quadruple bond between the Mo atoms, with an Mo-Mo distance of 2.101 (5) ̊. One half of the molecule constitutes the asymmetric unit and the carboxylate ligands define a paddlewheel structure, with similar O-C-O angles of 122.9 (3) and 123.7 (3)°. The interplanar angles between the acetate and 4-chlorophenoxy planes in the two independent ligands are 135.9(8) and 91.3(8)°, which is indicative of a dramatic difference in the orientation of the ligands. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.

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URI

https://hdl.handle.net/20.500.14740/5655

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Scopus: Year 1983-2021

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