Publication:
Cycloaddition-like reactions at germanium (1 0 0) surfaces: Adsorption and reaction of 1,5-cyclooctadiene

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Issued Date

2008

Resource Type

Article

File Type

application/pdf

ISSN

396028

DOI

10.1016/j.susc.2007.11.008

Other identifier(s)

2-s2.0-38349104566

Rights Holder(s)

มหาวิทยาลัยศรีนครินทรวิโรฒ

Bibliographic Citation

Surface Science. Vol 602, No.2 (2008), p.571-578

Suggested Citation

Prayongpan P., Stripe D.S., Greenlief C.M. Cycloaddition-like reactions at germanium (1 0 0) surfaces: Adsorption and reaction of 1,5-cyclooctadiene. Surface Science. Vol 602, No.2 (2008), p.571-578. doi:10.1016/j.susc.2007.11.008 Retrieved from: https://hdl.handle.net/20.500.14740/4150

Title

Cycloaddition-like reactions at germanium (1 0 0) surfaces: Adsorption and reaction of 1,5-cyclooctadiene

Author(s)

Prayongpan P.
 Stripe D.S.
 Greenlief C.M.

Abstract

The adsorption and reaction of 1,5-cyclooctadiene with the Ge(1 0 0) surface has been investigated. The subsequent surface reactions are followed by photoelectron spectroscopy and temperature programmed desorption. The bonding configuration is determined with photoelectron spectroscopy and compared with ab initio calculations. 1,5-Cyclooctadiene reacts with surface Ge dimers to form a four-membered ring structure at the surface at room temperature. Heating this surface results in some molecular desorption of 1,5-cyclooctadiene and the remaining surface species decompose at higher temperatures and desorb as either hydrocarbon species or molecular hydrogen. © 2007 Elsevier B.V. All rights reserved.

Subject(s)

Adsorption
 Chemical bonds
 Temperature programmed desorption
 Ultraviolet photoelectron spectroscopy
 X ray photoelectron spectroscopy
 Bonding configuration
 Hydrocarbon species
 Molecular desorption
 Germanium compounds

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URI

https://hdl.handle.net/20.500.14740/4150

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Scopus: Year 1983-2021

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