Publication: Causes of color in purple- And yellow- quartz
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Issued Date
2021
Resource Type
Language
eng
File Type
application/pdf
ISSN
17426588
Other identifier(s)
2-s2.0-85100730513
Rights Holder(s)
มหาวิทยาลัยศรีนครินทรวิโรฒ
Bibliographic Citation
Journal of Physics: Conference Series. Vol 1719, No.1 (2021)
Suggested Citation
Monarumit N., Sakkaravej S., Wanthanachaisaeng B., Saiyasombat C., Wongkokua W. Causes of color in purple- And yellow- quartz. Journal of Physics: Conference Series. Vol 1719, No.1 (2021). doi:10.1088/1742-6596/1719/1/012001 Retrieved from: https://hdl.handle.net/20.500.14740/7902
Abstract
Quartz is a variety of gemstone consisting of SiO2. The various colors of quartz are caused by Fe as a trace element. This study focused on the investigation of Fe oxidation states affecting colorations of purple- and yellow- quartz by X-ray absorption spectroscopy (XAS) and UV-Vis-NIR spectroscopy. The amethyst (purple- quartz) and citrine (yellow- quartz) were collected as the samples. As the XAS results, there was only Fe3+ oxidation state on both purple- and yellow- quartz considering with the absorption energy position at the Fe K-edge compared to the Fe-oxide chemical standards i.e., FeO and Fe2O3. However, the UV-Vis-NIR absorption spectra of the purple- and yellow- quartz were different. Therefore, we propose that the coloration of purple- and yellow- quartz was caused by Fe3+ oxidation states as the donor states at 3.59 eV and 2.28 eV with the different energy band gaps of the purple- and yellow- quartz that were 4.13 eV and 4.88 eV respectively derived from Tauc Plot method. © Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence.
