Publication: A Circular Economy Use of Durian Rind Waste for Cellulose Extraction and Its Application in Polylactic Acid (PLA) Biodegradable Composites
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Issued Date
2025-08-01
Resource Type
eISSN
27740226
Scopus ID
2-s2.0-105012212578
Journal Title
Trends in Sciences
Volume
22
Issue
8
Rights Holder(s)
SCOPUS
Bibliographic Citation
Trends in Sciences Vol.22 No.8 (2025)
Suggested Citation
Petchwattana N., Cha-Aim K., Rodphool K., Sang-On P., Lapsarn T., Sanetuntikul J., Sophonputtanaphoca S. A Circular Economy Use of Durian Rind Waste for Cellulose Extraction and Its Application in Polylactic Acid (PLA) Biodegradable Composites. Trends in Sciences Vol.22 No.8 (2025). doi:10.48048/tis.2025.10106 Retrieved from: https://hdl.handle.net/20.500.14740/21247
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Abstract
Durian rind is a food waste by-product left after consuming fruit flesh and can contribute to environmental pollution due to its slow decomposition and the large disposal area required because of its bulky shape. This study aims to evaluate the potential of durian rind as a cellulose source for producing biodegradable composites. Cellulose was extracted from the sample using a single-step alkali and hydrogen peroxide pretreatment under different conditions (temperature, residence time, and H<inf>2</inf>O<inf>2</inf> concentration). The optimal condition for achieving the highest cellulose content with minimal lignin contamination was treatment with 5 % NaOH in 7.5 % H<inf>2</inf>O<inf>2</inf> at 50 °C for 5 h. The extracted cellulose was milled and sieved to obtain 3 different particle sizes (< 250 µm (S), 250-425 µm (M), and > 425 µm (L)). All cellulose samples were characterized to determine their chemical and physical properties. FTIR spectra confirmed that most impurities in the raw material were removed after extraction. To evaluate the composite properties, polylactic acid (PLA)/cellulose composites with varying cellulose particle sizes and loadings were analyzed and compared to neat PLA. An increase in Young’s modulus was observed with the addition of cellulose, with the effect being more pronounced at lower cellulose loadings. Conversely, higher cellulose content negatively affected the composite properties, reducing tensile strength and elongation at break. This adverse effect was more significant with larger cellulose particles. FE-SEM analysis revealed that larger cellulose particles created larger interfacial voids, contributing to a decrease in tensile elongation at break. The incorporation of cellulose into PLA slightly elevated the glass transition temperature by approximately 1-2 °C. Moreover, the degree of crystallinity (X<inf>c</inf>) significantly increased with the addition of cellulose, with smaller cellulose particles being more effective in enhancing X<inf>c</inf>. PLA/cellulose composites may be suitable for applications as single-use plastics.