Publication: Optimization of ionic liquid 1-ethyl-3-methylimidazolium acetate pretreatment of Napier grass combined with acetic acid and ferric chloride under microwave radiation by response surface methodology
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Issued Date
2021
Resource Type
Language
eng
File Type
application/pdf
ISSN
21906815
Other identifier(s)
2-s2.0-85115164736
Rights Holder(s)
Scopus
Bibliographic Citation
Biomass Conversion and Biorefinery. Vol , No. (2021)
Suggested Citation
Chinwatpaiboon P., Saejao C., Boonsombuti A., Luengnaruemitchai A. Optimization of ionic liquid 1-ethyl-3-methylimidazolium acetate pretreatment of Napier grass combined with acetic acid and ferric chloride under microwave radiation by response surface methodology. Biomass Conversion and Biorefinery. Vol , No. (2021). doi:10.1007/s13399-021-01901-3 Retrieved from: https://hdl.handle.net/20.500.14740/7986
Abstract
Acidic aqueous ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate/acetic acid in combination with a metal salt (FeCl3) pretreatment was investigated for the pretreatment of Napier grass. This research focused on the effects of the FeCl3 concentration (20–100 mM), pretreatment time (10–190 min), and temperature (40–160 °C) during the pretreatment under microwave irradiation on the obtained total sugar yield after subsequent enzymatic hydrolysis. The optimum condition of these variables was determined by response surface methodology and compared with acidic aqueous IL pretreatment. The untreated and different pretreated NG samples were characterized using X-ray diffraction, scanning electron microscopy, Fourier-transform infrared spectroscopy, and thermogravimetric analyses. The effect of the type of anti-solvent (biomass regenerated solvent) on the obtained total reducing sugar yield by enhancing the cellulose content in the pretreated biomass was also studied. The results showed that an acidic aqueous IL could remove more lignin than the other pretreatments. The addition of FeCl3 in the acidic aqueous IL pretreatment had a significant effect on the total reducing sugar yield. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
Subject(s)
Chlorination
Chlorine compounds
Enzymatic hydrolysis
Fourier transform infrared spectroscopy
Ionic liquids
Microwave irradiation
Scanning electron microscopy
Surface properties
Thermogravimetric analysis
Volatile fatty acids
1-ethyl-3-methylimidazolium acetates
Aqueous ionic liquids
Cellulose content
Ferric chloride
Optimum conditions
Response surface methodology
Total reducing sugars
Total sugar yields
Iron compounds
Chlorine compounds
Enzymatic hydrolysis
Fourier transform infrared spectroscopy
Ionic liquids
Microwave irradiation
Scanning electron microscopy
Surface properties
Thermogravimetric analysis
Volatile fatty acids
1-ethyl-3-methylimidazolium acetates
Aqueous ionic liquids
Cellulose content
Ferric chloride
Optimum conditions
Response surface methodology
Total reducing sugars
Total sugar yields
Iron compounds