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DC Field | Value | Language |
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dc.contributor.author | Soponpong J. | |
dc.contributor.author | Dolsophon K. | |
dc.contributor.author | Thongpanchang C. | |
dc.contributor.author | Linden A. | |
dc.contributor.author | Thongpanchang T. | |
dc.date.accessioned | 2021-04-05T03:03:43Z | - |
dc.date.available | 2021-04-05T03:03:43Z | - |
dc.date.issued | 2019 | |
dc.identifier.issn | 404039 | |
dc.identifier.other | 2-s2.0-85059805363 | |
dc.identifier.uri | https://ir.swu.ac.th/jspui/handle/123456789/12493 | - |
dc.identifier.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85059805363&doi=10.1016%2fj.tetlet.2019.01.013&partnerID=40&md5=0218c68347ee364cccd5d50634cd65d9 | |
dc.description.abstract | The structure of a constrained bicyclic chiral derivatizing agent (CDA), 1,2,3,4-tetrahydro-1,4-epoxynaphthalene-1-carboxylic acid, THENA 1, was modified by replacing both exo-methylene protons with deuterium atoms. The modified CDA, THENA-d 2 2, could be used to assign the absolute configuration of chiral secondary alcohols with good reliability. Compared with THENA, the multiplicity of the methylene proton signals in the 1 H NMR spectra of THENA-d 2 derivatives is less complicated and the new CDA thus offers simpler NMR spectra for data interpretation. © 2019 Elsevier Ltd | |
dc.subject | 1,2,3,4 tetrahydro 1,4 epoxynaphthalene 1 carboxylic acid | |
dc.subject | carboxylic acid derivative | |
dc.subject | reagent | |
dc.subject | unclassified drug | |
dc.subject | Article | |
dc.subject | chiral chromatography | |
dc.subject | chirality | |
dc.subject | crystal structure | |
dc.subject | derivatization | |
dc.subject | proton nuclear magnetic resonance | |
dc.subject | reaction analysis | |
dc.subject | synthesis | |
dc.subject | X ray diffraction | |
dc.title | Application of deuterated THENA for assigning the absolute configuration of chiral secondary alcohols | |
dc.type | Article | |
dc.rights.holder | Scopus | |
dc.identifier.bibliograpycitation | Tetrahedron Letters. Vol 60, No.6 (2019), p.497-500 | |
dc.identifier.doi | 10.1016/j.tetlet.2019.01.013 | |
Appears in Collections: | Scopus 1983-2021 |
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