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Scandium(III)-Triflate-Catalyzed Pinacol-Pinacolone Rearrangement and Cyclization of 1,2-Diaryl-1,2-Ethanediol: A Versatile Synthesis of 1-Aryl-2,3-Dihydro-1H-3-Benzazepines

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dc.contributor.author Ieawsuwan W.
dc.contributor.author Pingaew R.
dc.contributor.author Kunkaewom S.
dc.contributor.author Ploypradith P.
dc.contributor.author Ruchirawat S.
dc.date.accessioned 2021-04-05T03:02:49Z
dc.date.available 2021-04-05T03:02:49Z
dc.date.issued 2019
dc.identifier.issn 21935807
dc.identifier.other 2-s2.0-85069704529
dc.identifier.uri https://ir.swu.ac.th/jspui/handle/123456789/12333
dc.identifier.uri https://www.scopus.com/inward/record.uri?eid=2-s2.0-85069704529&doi=10.1002%2fajoc.201900318&partnerID=40&md5=de1197bbad57176134c8ce6ffa94545c
dc.description.abstract An efficient scandium(III)-triflate-catalyzed pinacol-pinacolone rearrangement and cyclization of 1,2-diaryl-1,2-ethanediol has been developed, providing a variety of 2,3-dihydro-1H-3-benzazepine derivatives in good yields. The obtained products could be transformed to other valuable building blocks for the synthesis of some biologically active compounds or natural products. Moreover, this protocol was also successfully employed for the synthesis of the corresponding 1-phenyl-3,4,5,6-tetrahydrobenzo[d]azocine and 3-phenylisoquinoline products. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
dc.title Scandium(III)-Triflate-Catalyzed Pinacol-Pinacolone Rearrangement and Cyclization of 1,2-Diaryl-1,2-Ethanediol: A Versatile Synthesis of 1-Aryl-2,3-Dihydro-1H-3-Benzazepines
dc.type Article
dc.rights.holder Scopus
dc.identifier.bibliograpycitation Asian Journal of Organic Chemistry. Vol 8, No.8 (2019), p.1441-1447
dc.identifier.doi 10.1002/ajoc.201900318


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